SCHEDULED MAINTENANCE
M–H ⋯ OPPh3 hydrogen bonds are detected for a variety of cationic iridium hydrides of the type [IrH2L2(PPh3)2]+ and [IrH(bzquin)L′(PPh3)2]+ for which IR studies give estimates of the hydrogen-bond free energies of 10–13 kJ mol–1, the strongest being associated with those compounds having more electron-withdrawing ligands.
E. Peris and R. H. Crabtree, J. Chem. Soc., Chem. Commun., 1995, 2179 DOI: 10.1039/C39950002179
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