Issue 21, 1995
From the journal:

Journal of the Chemical Society, Chemical Communications

Transition-metal mediated functionalisation of a phosphaalkyne: crystal structure of [Re{[double bond, length half m-dash]C(But)P(H)OBF3}Br(PPh3)(η-C5H5)]

Nicholas Carr,   Michael Green,   Mary F. Mahon,   Cameron Jones  and  John F. Nixon  

Abstract

Treatment of the η2(3e)-vinyl complex [[graphic omitted]H(Ph)}Br(PPh3)(η-C5H5)] with HBF4·Et2O and the phosphaalkyne ButC[triple bond, length half m-dash]P affords the crystallographically characterised complex [[graphic omitted](H)OBF3}Br(PPh3)(η-C5H5)]1 formed via a novel reaction involving transfer of oxygen from a metal centre to a coordinated phosphaalkyne.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39950002191
Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 2191-2192

Permissions

Request permissions

Transition-metal mediated functionalisation of a phosphaalkyne: crystal structure of [Re{[double bond, length half m-dash]C(But)P(H)OBF3}Br(PPh3)(η-C5H5)]

N. Carr, M. Green, M. F. Mahon, C. Jones and J. F. Nixon, J. Chem. Soc., Chem. Commun., 1995, 2191 DOI: 10.1039/C39950002191

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements