Issue 47, 2013
From the journal:

Chemical Communications

Spectroscopic properties and reactivity of a mononuclear oxomanganese(iv) complex†

Domenick F. Leto,a   Rena Ingram,a   Victor W. Daya  and  Timothy A. Jackson*a  

* Corresponding authors

a Department of Chemistry, The University of Kansas, 1251 Wescoe Hall Drive, Lawrence, KS, USA
E-mail: taj@ku.edu
Fax: +1-785-864-5396
Tel: +1-785-864-3968

Abstract

A non-porphyrinic, mononuclear oxomanganese(IV) complex was generated at room temperature and characterized by spectroscopic methods. The MnIV[double bond, length as m-dash]O adduct is capable of activating C–H bonds by a H-atom transfer mechanism and is more reactive in this regard than most MnIV[double bond, length as m-dash]O species.

Graphical abstract: Spectroscopic properties and reactivity of a mononuclear oxomanganese(iv) complex

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Article information

DOI
https://doi.org/10.1039/C3CC00244F
Article type
Communication
Submitted
10 Jan 2013
Accepted
25 Apr 2013
First published
26 Apr 2013
This article is Open Access
Creative Commons BY license

Chem. Commun., 2013,49, 5378-5380

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Spectroscopic properties and reactivity of a mononuclear oxomanganese(IV) complex

D. F. Leto, R. Ingram, V. W. Day and T. A. Jackson, Chem. Commun., 2013, 49, 5378 DOI: 10.1039/C3CC00244F

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