Issue 37, 2013
From the journal:

Chemical Communications

Facile synthesis of a ruthenium assembly and its application for light-driven oxidation of alcohols in water†

Duobin Chaoab  and  Wen-Fu Fu*abc  

* Corresponding authors

a Key Laboratory of Photochemical Conversion and Optoelectronic Materials, CAS-HKU Joint Laboratory on New Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

b University of Chinese Academy of Sciences, Beijing 100049, P. R. China
E-mail: fuwf@mail.ipc.ac.cn

c College of Chemistry and Engineering, Yunnan Normal University, Kunming 650092, P. R. China

Abstract

A supramolecular assembly containing two light harvesting fragments [Ru(tpy)2]2+ and one catalytic unit [Ru(tpy)(bpy)Cl]+ was synthesized in a facile manner in 90% yield, and exhibited high photocatalytic product-selectivity compared with the corresponding bimolecular system in the light-driven oxidation of alcohols using [Co(NH3)5Cl]Cl2 as a sacrificial oxidant in water at room temperature.

Graphical abstract: Facile synthesis of a ruthenium assembly and its application for light-driven oxidation of alcohols in water

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Article information

DOI
https://doi.org/10.1039/C3CC00305A
Article type
Communication
Submitted
14 Jan 2013
Accepted
20 Mar 2013
First published
20 Mar 2013

Chem. Commun., 2013,49, 3872-3874

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Facile synthesis of a ruthenium assembly and its application for light-driven oxidation of alcohols in water

D. Chao and W. Fu, Chem. Commun., 2013, 49, 3872 DOI: 10.1039/C3CC00305A

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