Issue 27, 2013
From the journal:

Chemical Communications

A four-coordinate thionitrosyl complex of vanadium†

Ba L. Tran,a   Rick Thompson,a   Soumya Ghosh,a   Xinfeng Gao,a   Chun-Hsing Chen,a   Mu-Hyun Baika  and  Daniel J. Mindiola*a  

* Corresponding authors

a Department of Chemistry, Indiana University, 800 E. Kirkwood Avenue, Bloomington, Indiana, USA
E-mail: mindiola@indiana.edu
Fax: +1 812 855 8300
Tel: +1 812 855 4798, +1 812 855 2399

Abstract

Addition of elemental sulfur to the vanadium nitride [(nacnac)V[triple bond, length as m-dash]N(OAr)] forms the first thionitrosyl complex of vanadium, [(nacnac)V(NS)(OAr)]. Single crystal X-Ray diffraction studies and DFT calculations reveal an almost linear thionitrosyl ligand resulting from an extended π-resonance across the VNS moiety.

Graphical abstract: A four-coordinate thionitrosyl complex of vanadium

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Article information

DOI
https://doi.org/10.1039/C3CC38799B
Article type
Communication
Submitted
07 Dec 2012
Accepted
15 Feb 2013
First published
18 Feb 2013

Chem. Commun., 2013,49, 2768-2770

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A four-coordinate thionitrosyl complex of vanadium

B. L. Tran, R. Thompson, S. Ghosh, X. Gao, C. Chen, M. Baik and D. J. Mindiola, Chem. Commun., 2013, 49, 2768 DOI: 10.1039/C3CC38799B

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