Issue 19, 2013
From the journal:

Chemical Communications

Bespoke synthesis of unsymmetrical diaminoboranes by alkaline earth catalysis†

Peter Bellham,a   Michael S. Hill,*a   Gabriele Kociok-Köhna  and  David J. Liptrota  

* Corresponding authors

a Department of Chemistry, University of Bath, Claverton down, Bath, UK
E-mail: msh27@bath.ac.uk

Abstract

Heavier group 2 (Mg, Ca) bis(trimethylsilyl)amides are catalysts for the formation of unsymmetrical diaminoboranes, [(R2N)BH(NR′2)], by dehydrocoupling of amine boranes and protic amines; a process which is proposed to occur by a sequential metal-centred elimination–insertion–elimination mechanism.

Graphical abstract: Bespoke synthesis of unsymmetrical diaminoboranes by alkaline earth catalysis

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Article information

DOI
https://doi.org/10.1039/C3CC39072A
Article type
Communication
Submitted
19 Dec 2012
Accepted
17 Jan 2013
First published
21 Jan 2013

Chem. Commun., 2013,49, 1960-1962

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Bespoke synthesis of unsymmetrical diaminoboranes by alkaline earth catalysis

P. Bellham, M. S. Hill, G. Kociok-Köhn and D. J. Liptrot, Chem. Commun., 2013, 49, 1960 DOI: 10.1039/C3CC39072A

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