Issue 30, 2013
From the journal:

Chemical Communications

Chiral heterobimetallic complexes of carbodiphosphoranes and phosphinidene–carbene adducts†

Manuel Alcarazo,*a   Karin Radkowski,a   Gerlinde Mehler,a   Richard Goddarda  and  Alois Fürstner*a  

* Corresponding authors

a Max-Planck-Institut für Kohlenforschung, 45470 Mülheim an der Ruhr, Germany
E-mail: alcarazo@mpi-muelheim.mpg.de
Fax: +49 208 3062994
Tel: +49 208 3062428

Abstract

Heterobimetallic complexes derived from carbodiphosphoranes or phosphinidene–carbene adducts are reported, in which the central atom accepts two lone-pairs from two different donor ligands and – at the same time – donates two lone-pairs to two different metal centers. Therefore these complexes are carbogenic yet captodative chiral entities.

Graphical abstract: Chiral heterobimetallic complexes of carbodiphosphoranes and phosphinidene–carbene adducts

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC40382C
Article type
Communication
Submitted
16 Jan 2013
Accepted
21 Feb 2013
First published
11 Mar 2013

Chem. Commun., 2013,49, 3140-3142

Permissions

Request permissions

Chiral heterobimetallic complexes of carbodiphosphoranes and phosphinidene–carbene adducts

M. Alcarazo, K. Radkowski, G. Mehler, R. Goddard and A. Fürstner, Chem. Commun., 2013, 49, 3140 DOI: 10.1039/C3CC40382C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements