We report construction of monodisperse PAMAM-type dendrimers based on a dodecahydroxy closo-dodecaborane scaffold. The ideal sphericity and high functional group density of the icosahedral core permits ready access to hybrid dendrimers (dendritic closomers) having rigid, uniformly shaped exterior surfaces.
A. Pushechnikov, S. S. Jalisatgi and M. F. Hawthorne, Chem. Commun., 2013, 49, 3579 DOI: 10.1039/C3CC40597D
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