Issue 42, 2013
From the journal:

Chemical Communications

Carborane tuning of photophysical properties of phosphorescent iridium(iii) complexes†

Chao Shi,a   Huibin Sun,b   Qibai Jiang,a   Qiang Zhao,*b   Jingxia Wang,b   Wei Huang*b  and  Hong Yan*a  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China
E-mail: hyan1965@nju.edu.cn
Fax: +86 25-83314502

b Key Laboratory for Organic Electronics & Information Displays and Institute of Advanced Materials, Nanjing University of Posts and Telecommunications, Nanjing 210046, P. R. China
E-mail: iamqzhao@njupt.edu.cn, wei-huang@njupt.edu.cn
Fax: +86 25-85866396

Abstract

Both neutral and cationic iridium(III) complexes containing carborane units were synthesized. Bulky carboranes can significantly improve phosphorescence quantum yields of these complexes and the electronic effect of carboranes can evidently tune emission wavelengths of cationic complexes.

Graphical abstract: Carborane tuning of photophysical properties of phosphorescent iridium(iii) complexes

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Article information

DOI
https://doi.org/10.1039/C3CC40996A
Article type
Communication
Submitted
05 Feb 2013
Accepted
01 Mar 2013
First published
04 Mar 2013

Chem. Commun., 2013,49, 4746-4748

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Carborane tuning of photophysical properties of phosphorescent iridium(III) complexes

C. Shi, H. Sun, Q. Jiang, Q. Zhao, J. Wang, W. Huang and H. Yan, Chem. Commun., 2013, 49, 4746 DOI: 10.1039/C3CC40996A

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