Issue 40, 2013

A new photoclick reaction strategy: photo-induced catalysis of the thiol-Michael addition via a caged primary amine

Abstract

The utilization of 2-(2-nitrophenyl)propyloxycarbonyl (NPPOC) as a photolabile primary amine cage enables the thiol-Michael ‘click’ reaction to be photo-triggered. The photolabile amine exhibits efficient catalytic activity upon UV irradiation and is shown to initiate the photopolymerization of tetrathiol and diacrylate comonomers viaMichael addition.

Graphical abstract: A new photoclick reaction strategy: photo-induced catalysis of the thiol-Michael addition via a caged primary amine

Supplementary files

Article information

Article type
Communication
Submitted
10 Feb 2013
Accepted
08 Mar 2013
First published
08 Mar 2013
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2013,49, 4504-4506

A new photoclick reaction strategy: photo-induced catalysis of the thiol-Michael addition via a caged primary amine

W. Xi, M. Krieger, C. J. Kloxin and C. N. Bowman, Chem. Commun., 2013, 49, 4504 DOI: 10.1039/C3CC41123K

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