Issue 48, 2013

Boosted CO2 reaction with methanol to yield dimethyl carbonate over Mg–Al hydrotalcite-silica lyogels

Abstract

Nonimmobilized and immobilized Mg–Al hydrotalcite-like materials on silica lyogels were prepared and activated by calcination to be tested as catalysts in the direct carboxylation reaction of methanol. The HTs supported on silica lyogels showed an important improvement and high stability in the direct synthesis reaction of DMC from CO2 and MeOH.

Graphical abstract: Boosted CO2 reaction with methanol to yield dimethyl carbonate over Mg–Al hydrotalcite-silica lyogels

Supplementary files

Article information

Article type
Communication
Submitted
19 Feb 2013
Accepted
29 Apr 2013
First published
13 May 2013

Chem. Commun., 2013,49, 5489-5491

Boosted CO2 reaction with methanol to yield dimethyl carbonate over Mg–Al hydrotalcite-silica lyogels

D. C. Stoian, E. Taboada, J. Llorca, E. Molins, F. Medina and A. M. Segarra, Chem. Commun., 2013, 49, 5489 DOI: 10.1039/C3CC41298A

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