Issue 44, 2013

Solvent-induced lone pair activity tuning and vapoluminescence in a Pt2Pb cluster

Abstract

We report a novel cluster, [{Pt(C6F5)(bzq)}2Pb(Spy)2] 1, that displays reversible vapoluminescence to specific organic vapours; this behaviour can be related to the stereochemical activity of the lone pair around the PbII in the ground state and to the distinct distortion of the coordination environment (1 and 1solvent) upon photoexcitation.

Graphical abstract: Solvent-induced lone pair activity tuning and vapoluminescence in a Pt2Pb cluster

Supplementary files

Article information

Article type
Communication
Submitted
04 Mar 2013
Accepted
11 Apr 2013
First published
11 Apr 2013

Chem. Commun., 2013,49, 5067-5069

Solvent-induced lone pair activity tuning and vapoluminescence in a Pt2Pb cluster

J. R. Berenguer, E. Lalinde, A. Martín, M. Teresa Moreno, S. Ruiz, S. Sánchez and H. R. Shahsavari, Chem. Commun., 2013, 49, 5067 DOI: 10.1039/C3CC41638K

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