Issue 50, 2013

C–F bond formation with fluoride anions – highly selective iodofluorination of simple allenes

Abstract

A highly regioselective (up to 99 : 1) iodofluorination reaction of simple allenes occurs under mild conditions with Et3N·3HF or Py·9HF to afford 2-iodoalken-3-yl fluorides.

Graphical abstract: C–F bond formation with fluoride anions – highly selective iodofluorination of simple allenes

Supplementary files

Article information

Article type
Communication
Submitted
19 Mar 2013
Accepted
22 Apr 2013
First published
24 Apr 2013

Chem. Commun., 2013,49, 5651-5653

C–F bond formation with fluoride anions – highly selective iodofluorination of simple allenes

C. Xue, X. Jiang, C. Fu and S. Ma, Chem. Commun., 2013, 49, 5651 DOI: 10.1039/C3CC42014K

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