Issue 55, 2013

Cyclometalated metal–organic frameworks as stable and reusable heterogeneous catalysts for allylic N-alkylation of amines

Abstract

Metal–organic frameworks (MOFs) functionalized via Ir(I) cyclometalation are shown to be effective as heterogeneous catalysts for the allylic N-alkylation of various amines. The MOF catalysts are one of the first and most effective MOF-based heterogeneous organometallic catalysts for the direct formation of C–N bonds. In addition, these MOFs represent a rare, stable and reusable, class of reactive Ir catalysts.

Graphical abstract: Cyclometalated metal–organic frameworks as stable and reusable heterogeneous catalysts for allylic N-alkylation of amines

Supplementary files

Article information

Article type
Communication
Submitted
23 Mar 2013
Accepted
25 May 2013
First published
29 May 2013

Chem. Commun., 2013,49, 6128-6130

Cyclometalated metal–organic frameworks as stable and reusable heterogeneous catalysts for allylic N-alkylation of amines

P. V. Dau and S. M. Cohen, Chem. Commun., 2013, 49, 6128 DOI: 10.1039/C3CC42119H

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