Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO2 selectivity

Suvendu Sekhar Mondal; Asamanjoy Bhunia; Igor A. Baburin; Christian Jäger; Alexandra Kelling; Uwe Schilde; Gotthard Seifert; Christoph Janiak; Hans-Jürgen Holdt

doi:10.1039/C3CC42156B

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Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO₂ selectivity†

Suvendu Sekhar Mondal,^a Asamanjoy Bhunia,^b Igor A. Baburin,^c Christian Jäger,^d Alexandra Kelling,^a Uwe Schilde,^a Gotthard Seifert,^c Christoph Janiak^b and Hans-Jürgen Holdt*^a

Author affiliations

* Corresponding authors

^a Institut für Chemie, Anorganische Chemie, Universität Potsdam, Karl-Liebknecht-Straße 24-25, 14476 Potsdam, Germany
E-mail: holdt@uni-potsdam.de
Fax: +49 331-977-5055
Tel: +49 331-977-5180

^b Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-Universität Düsseldorf, 40204 Düsseldorf, Germany

^c Institut für Physikalische Chemie und Elektrochemie, Technische Universität Dresden, 01062 Dresden, Germany

^d BAM Federal Institute for Materials Research and Testing, 12489 Berlin, Germany

Abstract

A new imidazolate-4-amide-5-imidate based MOF, IFP-7, is generated, having flexible methoxy groups, which act as molecular gates for guest molecules. This allows highly selective CO₂ sorption over N₂ and CH₄ gases.

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Article information

DOI: https://doi.org/10.1039/C3CC42156B
Article type: Communication
Submitted: 26 Mar 2013
Accepted: 28 Jun 2013
First published: 28 Jun 2013

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Chem. Commun., 2013,49, 7599-7601

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Gate effects in a hexagonal zinc-imidazolate-4-amide-5-imidate framework with flexible methoxy substituents and CO₂ selectivity

S. S. Mondal, A. Bhunia, I. A. Baburin, C. Jäger, A. Kelling, U. Schilde, G. Seifert, C. Janiak and H. Holdt, Chem. Commun., 2013, 49, 7599 DOI: 10.1039/C3CC42156B

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Chemical Communications