Efficient epoxidation of olefins by H2O2 catalyzed by iron “helmet” phthalocyanines

Igor Y. Skobelev; Evgeny V. Kudrik; Olga V. Zalomaeva; Florian Albrieux; Pavel Afanasiev; Oxana A. Kholdeeva; Alexander B. Sorokin

doi:10.1039/C3CC42301H

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Efficient epoxidation of olefins by H₂O₂ catalyzed by iron “helmet” phthalocyanines†

Igor Y. Skobelev,^ab Evgeny V. Kudrik,^ac Olga V. Zalomaeva,^b Florian Albrieux,^d Pavel Afanasiev,^a Oxana A. Kholdeeva^b and Alexander B. Sorokin*^a

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* Corresponding authors

^a Institut de Recherches sur la Catalyse et l'Environnement de Lyon (IRCELYON), UMR 5256, CNRS-Université Lyon 1, 2, av. A. Einstein, 69626 Villeurbanne Cedex, France
E-mail: alexander.sorokin@ircelyon.univ-lyon1.fr
Fax: +33 472445399
Tel: +33 472445337

^b Boreskov Institute of Catalysis, pr. Lavrentieva 5, Novosibirsk, Russia

^c Institute of Macroheterocyclic Compounds, Ivanovo State University of Chemistry and Technology, 7, av. F. Engels, Ivanovo, Russia

^d Université Lyon 1, UMR 5246, Centre Commun de Spectrométrie de Masse, 43 bd du 11 Novembre 1918, 69622 Villeurbanne cedex, France

Abstract

High yields of epoxides were obtained in the oxidation of a large range of olefins using 1.2–2 equiv. of H₂O₂ in the presence of iron helmet phthalocyanines. The involvement of high-valent iron oxo species was evidenced using cryospray mass spectrometry.

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Article information

DOI: https://doi.org/10.1039/C3CC42301H
Article type: Communication
Submitted: 29 Mar 2013
Accepted: 29 Apr 2013
First published: 01 May 2013

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Chem. Commun., 2013,49, 5577-5579

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Efficient epoxidation of olefins by H₂O₂ catalyzed by iron “helmet” phthalocyanines

I. Y. Skobelev, E. V. Kudrik, O. V. Zalomaeva, F. Albrieux, P. Afanasiev, O. A. Kholdeeva and A. B. Sorokin, Chem. Commun., 2013, 49, 5577 DOI: 10.1039/C3CC42301H

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Chemical Communications