Issue 65, 2013
From the journal:

Chemical Communications

Visible-light-induced hydroalkoxymethylation of electron-deficient alkenes by photoredox catalysis†

Kazuki Miyazawa,a   Yusuke Yasu,a   Takashi Koike*a  and  Munetaka Akita*a  

* Corresponding authors

a Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan
E-mail: koike.t.ad@m.titech.ac.jp, makita@res.titech.ac.jp
Fax: +81-45-924-5230
Tel: +81-45-924-5230

Abstract

Hydroalkoxymethylation of electron-deficient alkenes using alkoxymethyltrifluoroborates by photoredox catalysis has been developed. Highly reactive alkoxymethyl radicals can be easily generated from oxidation of alkoxymethyltrifluoroborates via a visible-light-induced SET process.

Graphical abstract: Visible-light-induced hydroalkoxymethylation of electron-deficient alkenes by photoredox catalysis

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Article information

DOI
https://doi.org/10.1039/C3CC42695E
Article type
Communication
Submitted
12 Apr 2013
Accepted
18 Jun 2013
First published
19 Jun 2013

Chem. Commun., 2013,49, 7249-7251

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Visible-light-induced hydroalkoxymethylation of electron-deficient alkenes by photoredox catalysis

K. Miyazawa, Y. Yasu, T. Koike and M. Akita, Chem. Commun., 2013, 49, 7249 DOI: 10.1039/C3CC42695E

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