Issue 56, 2013
From the journal:

Chemical Communications

Spin state modulation of iron spin crossover complexes via hydrogen-bonding self-assembly†

Michael C. Young,a   Erica Liew,a   Jonathan Ashby,a   Kelsi E. McCoya  and  Richard J. Hooley*a  

* Corresponding authors

a Department of Chemistry, University of California - Riverside, 501 Big Springs Rd., Riverside, CA, USA
E-mail: richard.hooley@ucr.edu

Abstract

Iron complexes derived from 6-diaminotriazyl-2,2′-bipyridines display spin crossover behaviour, and hydrogen bonding-controlled self-assembly with a suitable barbiturate partner can modulate the crossover from mixed low and high spin to high spin. This system is the first to use solution-phase self-assembly of complementary hydrogen-bonding organic species to modulate spin state.

Graphical abstract: Spin state modulation of iron spin crossover complexes via hydrogen-bonding self-assembly

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Article information

DOI
https://doi.org/10.1039/C3CC42851F
Article type
Communication
Submitted
17 Apr 2013
Accepted
30 May 2013
First published
31 May 2013

Chem. Commun., 2013,49, 6331-6333

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Spin state modulation of iron spin crossover complexes via hydrogen-bonding self-assembly

M. C. Young, E. Liew, J. Ashby, K. E. McCoy and R. J. Hooley, Chem. Commun., 2013, 49, 6331 DOI: 10.1039/C3CC42851F

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