Issue 61, 2013
From the journal:

Chemical Communications

Carbonylation of the simplest persistent diaminocarbene†‡

Tim Schulz,a   Christian Färber,a   Michael Leibold,a   Clemens Bruhn,a   Wolfgang Baumann,b   Detlef Selent,b   Timo Porsch,c   Max C. Holthausenc  and  Ulrich Siemeling*a  

* Corresponding authors

a Institute of Chemistry, University of Kassel, Heinrich-Plett-Str. 40, D-34132 Kassel, Germany
E-mail: siemeling@uni-kassel.de

b Leibniz Institute for Catalysis e. V. at the University of Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany

c Institut für Anorganische und Analytische Chemie, Johann Wolfgang Goethe-Universität Frankfurt, Max-von-Laue-Str. 7, D-60438 Frankfurt am Main, Germany

Abstract

The reactions of the acyclic diaminocarbenes (Me2N)2C and (Ph2N)(iPr2N)C with CO proceed in a 2 : 1 stoichiometric ratio, affording unprecedented betainic oxyallyl species of type [(R2N)2C]2CO.

Graphical abstract: Carbonylation of the simplest persistent diaminocarbene

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC42888E
Article type
Communication
Submitted
18 Apr 2013
Accepted
11 May 2013
First published
13 May 2013

Chem. Commun., 2013,49, 6834-6836

Permissions

Request permissions

Carbonylation of the simplest persistent diaminocarbene

T. Schulz, C. Färber, M. Leibold, C. Bruhn, W. Baumann, D. Selent, T. Porsch, M. C. Holthausen and U. Siemeling, Chem. Commun., 2013, 49, 6834 DOI: 10.1039/C3CC42888E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements