Issue 58, 2013
From the journal:

Chemical Communications

Preparation of a semiquinonate-bridged diiron(ii) complex and elucidation of its geometric and electronic structures†

Amanda E. Baum,a   Sergey V. Lindemana  and  Adam T. Fiedler*a  

* Corresponding authors

a Department of Chemistry, Marquette University, 535 N. 14th St., Milwaukee, WI 53233, USA
E-mail: adam.fiedler@marquette.edu
Fax: +1-414-288-7066

Abstract

The synthesis and crystal structure of a diiron(II) complex containing a bridging semiquinonate radical are presented. The unique electronic structure of this S = 7/2 complex is examined with spectroscopic (absorption, EPR, resonance Raman) and computational methods.

Graphical abstract: Preparation of a semiquinonate-bridged diiron(ii) complex and elucidation of its geometric and electronic structures

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Article information

DOI
https://doi.org/10.1039/C3CC42980F
Article type
Communication
Submitted
22 Apr 2013
Accepted
01 Jun 2013
First published
03 Jun 2013

Chem. Commun., 2013,49, 6531-6533

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Preparation of a semiquinonate-bridged diiron(II) complex and elucidation of its geometric and electronic structures

A. E. Baum, S. V. Lindeman and A. T. Fiedler, Chem. Commun., 2013, 49, 6531 DOI: 10.1039/C3CC42980F

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