Issue 59, 2013
From the journal:

Chemical Communications

Anion-directed assembly of a non-interpenetrated square-grid metal–organic framework with nanoscale porosity†

Atanu Mitra,a   Christian T. Hubley,a   Dillip K. Panda,a   Ronald J. Clarka  and  Sourav Saha*a  

* Corresponding authors

a Department of Chemistry and Biochemistry and Integrative NanoScience Institute, Florida State University, 95 Chieftan Way, Tallahassee, FL 32306-4390, USA
E-mail: saha@chem.fsu.edu
Tel: +1 850 645 8616

Abstract

A non-interpenetrated square grid metal–organic framework (MOF) comprised of octahedral Zn(II) ions and linear N,N′-di(4-pyridyl)-1,4,5,8-naphthalenediimide (DPNDI) ligands was formed in the presence of noncoordinating perchlorate counterions that occupied the cavities of the porous network by forming CH⋯anion hydrogen bonds with DPNDI ligands, whereas a linear coordination polymer was obtained when Zn(II)-coordinated nitrate ions were present as counterions.

Graphical abstract: Anion-directed assembly of a non-interpenetrated square-grid metal–organic framework with nanoscale porosity

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Article information

DOI
https://doi.org/10.1039/C3CC43178A
Article type
Communication
Submitted
29 Apr 2013
Accepted
30 May 2013
First published
31 May 2013

Chem. Commun., 2013,49, 6629-6631

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Anion-directed assembly of a non-interpenetrated square-grid metal–organic framework with nanoscale porosity

A. Mitra, C. T. Hubley, D. K. Panda, R. J. Clark and S. Saha, Chem. Commun., 2013, 49, 6629 DOI: 10.1039/C3CC43178A

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