Issue 59, 2013

Direct synthesis of pyridines and quinolines by coupling of γ-amino-alcohols with secondary alcohols liberating H2 catalyzed by ruthenium pincer complexes

Abstract

A novel, one-step synthesis of substituted pyridine- and quinoline-derivatives was achieved by acceptorless dehydrogenative coupling of γ-aminoalcohols with secondary alcohols. The reaction involves consecutive C–N and C–C bond formation, catalyzed by a bipyridyl-based ruthenium pincer complex with a base.

Graphical abstract: Direct synthesis of pyridines and quinolines by coupling of γ-amino-alcohols with secondary alcohols liberating H2 catalyzed by ruthenium pincer complexes

Supplementary files

Article information

Article type
Communication
Submitted
01 May 2013
Accepted
24 May 2013
First published
28 May 2013

Chem. Commun., 2013,49, 6632-6634

Direct synthesis of pyridines and quinolines by coupling of γ-amino-alcohols with secondary alcohols liberating H2 catalyzed by ruthenium pincer complexes

D. Srimani, Y. Ben-David and D. Milstein, Chem. Commun., 2013, 49, 6632 DOI: 10.1039/C3CC43227K

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