Issue 74, 2013
From the journal:

Chemical Communications

A homochiral porous metal–organic framework for enantioselective adsorption of mandelates and photocyclizaton of tropolone ethers†

Yongwu Peng,a   Tengfei Gonga  and  Yong Cui*a  

* Corresponding authors

a School of Chemistry and Chemical Technology and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China
E-mail: yongcui@sjtu.edu.cn
Fax: +86 21-5474-1297

Abstract

A chiral porous metal–organic framework of an axially C2-symmetric 1,1′-biphenol ligand is constructed and can be used as a solid-state host to enanioselectively adsorb mandelates with up to 93.1% ee and to entrap achiral tropolone ethers and induce their asymmetric photocyclization with up to 98.5% ee.

Graphical abstract: A homochiral porous metal–organic framework for enantioselective adsorption of mandelates and photocyclizaton of tropolone ethers

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Article information

DOI
https://doi.org/10.1039/C3CC43549K
Article type
Communication
Submitted
12 May 2013
Accepted
15 Jul 2013
First published
16 Jul 2013

Chem. Commun., 2013,49, 8253-8255

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A homochiral porous metal–organic framework for enantioselective adsorption of mandelates and photocyclizaton of tropolone ethers

Y. Peng, T. Gong and Y. Cui, Chem. Commun., 2013, 49, 8253 DOI: 10.1039/C3CC43549K

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