Issue 69, 2013
From the journal:

Chemical Communications

Palladium-catalyzed para-selective arylation of phenols with aryl iodides in water†

Zhiqing Wu,a   Feihua Luo,a   Si Chen,a   Zhengkai Li,a   Haifeng Xianga  and  Xiangge Zhou*ab  

* Corresponding authors

a Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064, P. R. China
E-mail: zhouxiangge@scu.edu.cn

b Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China

Abstract

Highly para-selective palladium-catalyzed direct arylation of phenols with aryl iodides was demonstrated by taking advantage of the formal inverse direct arylation strategy. A series of 4-aryl phenols were synthesised by employing water as a “green” solvent under mild reaction conditions.

Graphical abstract: Palladium-catalyzed para-selective arylation of phenols with aryl iodides in water

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Article information

DOI
https://doi.org/10.1039/C3CC44345K
Article type
Communication
Submitted
09 Jun 2013
Accepted
03 Jul 2013
First published
04 Jul 2013

Chem. Commun., 2013,49, 7653-7655

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Palladium-catalyzed para-selective arylation of phenols with aryl iodides in water

Z. Wu, F. Luo, S. Chen, Z. Li, H. Xiang and X. Zhou, Chem. Commun., 2013, 49, 7653 DOI: 10.1039/C3CC44345K

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