Coherent manipulation of spin qubits based on polyoxometalates: the case of the single ion magnet [GdW30P5O110]14−

José J. Baldoví; Salvador Cardona-Serra; Juan M. Clemente-Juan; Eugenio Coronado; Alejandro Gaita-Ariño; Helena Prima-García

doi:10.1039/C3CC44838J

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Coherent manipulation of spin qubits based on polyoxometalates: the case of the single ion magnet [GdW₃₀P₅O₁₁₀]¹⁴⁻†

José J. Baldoví,^a Salvador Cardona-Serra,^a Juan M. Clemente-Juan,^a Eugenio Coronado,*^a Alejandro Gaita-Ariño^a and Helena Prima-García*^a

Author affiliations

* Corresponding authors

^a Instituto de Ciencia Molecular, University of Valencia, c/Cat. José Beltrán, Paterna, Spain

Abstract

Polyoxometalate single ion magnet [GdW₃₀P₅O₁₁₀]¹⁴⁻ (1) has been studied by generalized Rabi oscillation experiments. It was possible to increase the number of coherent rotations tenfold through matching the Rabi frequency with the frequency of the proton. Achieving high coherence with polyoxometalate chemistry, we show its excellent potential not only for the storage of quantum information but even for the realization of quantum algorithms.

This article is part of the themed collection: Molecular Spintronics

Download options Please wait...

Supplementary files

Supplementary information PDF (654K)

Additions and corrections

Addition HTM (3K)

Article information

DOI: https://doi.org/10.1039/C3CC44838J
Article type: Communication
Submitted: 27 Jun 2013
Accepted: 31 Jul 2013
First published: 01 Aug 2013

Download Citation

Chem. Commun., 2013,49, 8922-8924

Permissions

Request permissions

Coherent manipulation of spin qubits based on polyoxometalates: the case of the single ion magnet [GdW₃₀P₅O₁₁₀]¹⁴⁻

J. J. Baldoví, S. Cardona-Serra, J. M. Clemente-Juan, E. Coronado, A. Gaita-Ariño and H. Prima-García, Chem. Commun., 2013, 49, 8922 DOI: 10.1039/C3CC44838J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications