Issue 83, 2013

Modelling electric field control of the spin state in the mixed-valence polyoxometalate [GeV14O40]8−

Abstract

The two-electron reduced mixed-valence polyoxometalate [GeV14O40]8− presents an unusual paramagnetic behaviour as a consequence of the partial trapping of these electrons. The effect of applying an electric field is that of inducing antiferromagnetic coupling between the two delocalized electronic spins.

Graphical abstract: Modelling electric field control of the spin state in the mixed-valence polyoxometalate [GeV14O40]8−

Article information

Article type
Communication
Submitted
28 Jun 2013
Accepted
23 Aug 2013
First published
23 Aug 2013

Chem. Commun., 2013,49, 9621-9623

Modelling electric field control of the spin state in the mixed-valence polyoxometalate [GeV14O40]8−

S. Cardona-Serra, J. M. Clemente-Juan, A. Gaita-Ariño, N. Suaud, O. Svoboda and E. Coronado, Chem. Commun., 2013, 49, 9621 DOI: 10.1039/C3CC44859B

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