Issue 25, 2014

The effect of pyridine modification of Ni–DOBDC on CO2 capture under humid conditions

Abstract

The metal–organic framework Ni–DOBDC was modified with pyridine molecules to make the normally hydrophilic internal surface more hydrophobic. Experiments and molecular simulations show that the pyridine modification reduces H2O adsorption while retaining substantial CO2 capacity under the conditions of interest for carbon capture from flue gas.

Graphical abstract: The effect of pyridine modification of Ni–DOBDC on CO2 capture under humid conditions

Supplementary files

Article information

Article type
Communication
Submitted
02 Jul 2013
Accepted
04 Feb 2014
First published
04 Feb 2014

Chem. Commun., 2014,50, 3296-3298

Author version available

The effect of pyridine modification of Ni–DOBDC on CO2 capture under humid conditions

Y. Bae, J. Liu, C. E. Wilmer, H. Sun, A. N. Dickey, M. B. Kim, A. I. Benin, R. R. Willis, D. Barpaga, M. D. LeVan and R. Q. Snurr, Chem. Commun., 2014, 50, 3296 DOI: 10.1039/C3CC44954H

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