Issue 90, 2013
From the journal:

Chemical Communications

A functionalized MIL-101(Cr) metal–organic framework for enhanced hydrogen release from ammonia borane at low temperature†

Liang Gao,a   Chi-Ying Vanessa Li,a   Hoi Yunga  and  Kwong-Yu Chan*a  

* Corresponding authors

a Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong
E-mail: hrsccky@hku.hk

Abstract

Hydrogen released from ammonia borane in MIL-101(Cr) can be significantly improved by the attached amino and amide groups. The release with minimum impurities starts at 68 °C, reaching 1.6 equivalent of ammonia borane at 85 °C for the amino modified MOFs (NH2-MIL-101).

Graphical abstract: A functionalized MIL-101(Cr) metal–organic framework for enhanced hydrogen release from ammonia borane at low temperature

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Article information

DOI
https://doi.org/10.1039/C3CC45719B
Article type
Communication
Submitted
26 Jul 2013
Accepted
23 Sep 2013
First published
07 Oct 2013

Chem. Commun., 2013,49, 10629-10631

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A functionalized MIL-101(Cr) metal–organic framework for enhanced hydrogen release from ammonia borane at low temperature

L. Gao, C. V. Li, H. Yung and K. Chan, Chem. Commun., 2013, 49, 10629 DOI: 10.1039/C3CC45719B

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