Issue 89, 2013
From the journal:

Chemical Communications

Operando magnetic resonance: monitoring the evolution of conversion and product distribution during the heterogeneous catalytic ethene oligomerisation reaction†

S. Tegan Roberts,a   Matthew P. Renshaw,a   Michal Lutecki,a   James McGregor,‡a   Andrew J. Sederman,a   Mick D. Mantlea  and  Lynn F. Gladden*a  

* Corresponding authors

a Department of Chemical Engineering and Biotechnology, University of Cambridge, Pembroke Street, Cambridge, UK
E-mail: lfg1@cam.ac.uk
Fax: +44 (0)1223 334796
Tel: +44 (0)1223 334777

Abstract

Operando magnetic resonance (MR) spectroscopy has been used to follow an ethene oligomerisation reaction performed at 110 °C, 28 barg over a 1 wt% Ni/SiO2–Al2O3 catalyst. Spectra acquired over the timecourse of the reaction allow the calculation of conversion and product distribution as a function of time-on-stream.

Graphical abstract: Operando magnetic resonance: monitoring the evolution of conversion and product distribution during the heterogeneous catalytic ethene oligomerisation reaction

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Article information

DOI
https://doi.org/10.1039/C3CC45896B
Article type
Communication
Submitted
01 Aug 2013
Accepted
23 Sep 2013
First published
24 Sep 2013

Chem. Commun., 2013,49, 10519-10521

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Operando magnetic resonance: monitoring the evolution of conversion and product distribution during the heterogeneous catalytic ethene oligomerisation reaction

S. T. Roberts, M. P. Renshaw, M. Lutecki, J. McGregor, A. J. Sederman, M. D. Mantle and L. F. Gladden, Chem. Commun., 2013, 49, 10519 DOI: 10.1039/C3CC45896B

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