Issue 84, 2013

Enantioselective ring-opening of meso-epoxides by aromatic amines catalyzed by a homochiral metal–organic framework

Abstract

The enantioselective ring-opening of meso-epoxides by aromatic amines was achieved by using a new chiral metal–organic framework UTSA-32a. The corresponding α-hydroxyamines were obtained with good yields and ee values (up to 89% ee).

Graphical abstract: Enantioselective ring-opening of meso-epoxides by aromatic amines catalyzed by a homochiral metal–organic framework

Supplementary files

Article information

Article type
Communication
Submitted
05 Aug 2013
Accepted
28 Aug 2013
First published
29 Aug 2013

Chem. Commun., 2013,49, 9836-9838

Enantioselective ring-opening of meso-epoxides by aromatic amines catalyzed by a homochiral metal–organic framework

S. Regati, Y. He, M. Thimmaiah, P. Li, S. Xiang, B. Chen and J. C. Zhao, Chem. Commun., 2013, 49, 9836 DOI: 10.1039/C3CC45988H

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