Issue 3, 2014

Investigations on the crystal plane effect of ceria on gold catalysis in the oxidative dehydrogenation of alcohols and amines in the liquid phase

Abstract

Gold nanoparticles supported on ceria{110} crystal planes were more reactive than on ceria{111} and {100} in the oxidative dehydrogenation of alcohols. Kinetic analysis and a Hammett plot suggest that hydride transfer is involved, and the cationic gold is catalytically active.

Graphical abstract: Investigations on the crystal plane effect of ceria on gold catalysis in the oxidative dehydrogenation of alcohols and amines in the liquid phase

Supplementary files

Article information

Article type
Communication
Submitted
13 Aug 2013
Accepted
28 Oct 2013
First published
28 Oct 2013

Chem. Commun., 2014,50, 292-294

Investigations on the crystal plane effect of ceria on gold catalysis in the oxidative dehydrogenation of alcohols and amines in the liquid phase

M. Wang, F. Wang, J. Ma, M. Li, Z. Zhang, Y. Wang, X. Zhang and J. Xu, Chem. Commun., 2014, 50, 292 DOI: 10.1039/C3CC46180G

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