Issue 2, 2014
From the journal:

Chemical Communications

A novel chiral yttrium complex with a tridentate linked amido-indenyl ligand for intramolecular hydroamination†

Zhuo Chai,a   Dezhi Hua,a   Kui Li,a   Jiang Chua  and  Gaosheng Yang*a  

* Corresponding authors

a The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, Institute of Organic Chemistry, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, China
E-mail: gshyang@mail.ahnu.edu.cn
Tel: +86 553 3869310

Abstract

A new chiral silicon-linked tridentate amido-indenyl ligand was developed from indene and enantiopure 1,2-cyclohexanediamine. Its yttrium complex was synthesized, characterized and applied to efficiently catalyze the intramolecular hydroamination of non-activated olefins with up to 97% ee.

Graphical abstract: A novel chiral yttrium complex with a tridentate linked amido-indenyl ligand for intramolecular hydroamination

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Article information

DOI
https://doi.org/10.1039/C3CC47006G
Article type
Communication
Submitted
13 Sep 2013
Accepted
22 Oct 2013
First published
22 Oct 2013

Chem. Commun., 2014,50, 177-179

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A novel chiral yttrium complex with a tridentate linked amido-indenyl ligand for intramolecular hydroamination

Z. Chai, D. Hua, K. Li, J. Chu and G. Yang, Chem. Commun., 2014, 50, 177 DOI: 10.1039/C3CC47006G

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