Issue 96, 2013

2-Iodoxybenzoic acid organosulfonates: preparation, X-ray structure and reactivity of new, powerful hypervalent iodine(v) oxidants

Abstract

New powerful hypervalent iodine(V) oxidants, tosylate and mesylate derivatives of 2-iodoxybenzoic acid (IBX), were prepared by the reaction of IBX with the corresponding sulfonic acids. Single crystal X-ray crystallography of the diacetate derivative of IBX-tosylate revealed an unusual heptacoordinated iodine geometry without any significant intermolecular secondary interactions.

Graphical abstract: 2-Iodoxybenzoic acid organosulfonates: preparation, X-ray structure and reactivity of new, powerful hypervalent iodine(v) oxidants

Supplementary files

Article information

Article type
Communication
Submitted
16 Sep 2013
Accepted
09 Oct 2013
First published
10 Oct 2013

Chem. Commun., 2013,49, 11269-11271

2-Iodoxybenzoic acid organosulfonates: preparation, X-ray structure and reactivity of new, powerful hypervalent iodine(V) oxidants

M. S. Yusubov, D. Yu. Svitich, A. Yoshimura, V. N. Nemykin and V. V. Zhdankin, Chem. Commun., 2013, 49, 11269 DOI: 10.1039/C3CC47090C

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