Issue 15, 2014

Highly efficient blue-green delayed fluorescence from copper(i) thiolate complexes: luminescence color alteration by orientation change of the aryl ring

Abstract

Highly emissive three-coordinate thiolate copper(I) complexes are synthesized and characterized. The Cu(I) complexes emit intense blue-green delayed fluorescence with high photoluminescence quantum yields of approximately 1.0 at both 293 K and 77 K in the solid state, whereas orange emission at 293 K in solution is observed.

Graphical abstract: Highly efficient blue-green delayed fluorescence from copper(i) thiolate complexes: luminescence color alteration by orientation change of the aryl ring

Supplementary files

Article information

Article type
Communication
Submitted
14 Oct 2013
Accepted
01 Dec 2013
First published
02 Dec 2013

Chem. Commun., 2014,50, 1801-1803

Highly efficient blue-green delayed fluorescence from copper(I) thiolate complexes: luminescence color alteration by orientation change of the aryl ring

M. Osawa, Chem. Commun., 2014, 50, 1801 DOI: 10.1039/C3CC47871H

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