Issue 18, 2014

High gas storage capacities and stepwise adsorption in a UiO type metal–organic framework incorporating Lewis basic bipyridyl sites

Abstract

A UiO type MOF with Lewis basic bipyridyl sites was synthesized and structurally characterized. After being activated by Soxhlet-extraction, this MOF exhibits high storage capacities for H2, CH4 and CO2, and shows unusual stepwise adsorption for liquid CO2 and solvents, indicating a sequential filling mechanism on different adsorption sites.

Graphical abstract: High gas storage capacities and stepwise adsorption in a UiO type metal–organic framework incorporating Lewis basic bipyridyl sites

Supplementary files

Article information

Article type
Communication
Submitted
29 Oct 2013
Accepted
10 Dec 2013
First published
10 Dec 2013

Chem. Commun., 2014,50, 2304-2307

High gas storage capacities and stepwise adsorption in a UiO type metal–organic framework incorporating Lewis basic bipyridyl sites

L. Li, S. Tang, C. Wang, X. Lv, M. Jiang, H. Wu and X. Zhao, Chem. Commun., 2014, 50, 2304 DOI: 10.1039/C3CC48275H

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