Issue 9, 2014
From the journal:

Chemical Communications

Stepwise addition of difluorocarbene to a transition metal centre†

Graham M. Lee,a   Daniel J. Harrison,a   Ilia Korobkova  and  R. Tom Baker*a  

* Corresponding authors

a Department of Chemistry and Centre for Catalysis Research and Innovation, University of Ottawa, 30 Marie Curie, Ottawa, Ontario K1N 6N5, Canada
E-mail: rbaker@uottawa.ca

Abstract

The Ruppert–Prakash reagent (Me3SiCF3) is used to introduce difluorocarbene (CF2) and tetrafluoroethylene (TFE) ligands to cobalt(I) metal centres, whereby the TFE ligand is generated via [2+1] cycloaddition between [Co][double bond, length as m-dash]CF2 and CF2.

Graphical abstract: Stepwise addition of difluorocarbene to a transition metal centre

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Article information

DOI
https://doi.org/10.1039/C3CC48468H
Article type
Communication
Submitted
05 Nov 2013
Accepted
02 Dec 2013
First published
10 Dec 2013

Chem. Commun., 2014,50, 1128-1130

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Stepwise addition of difluorocarbene to a transition metal centre

G. M. Lee, D. J. Harrison, I. Korobkov and R. T. Baker, Chem. Commun., 2014, 50, 1128 DOI: 10.1039/C3CC48468H

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