Issue 20, 2014

An unsolvated buckycatcher and its first dianion

Abstract

The X-ray crystallographic study of C60H28 consisting of two tethered corannulene bowls revealed a unique solid-state packing based on tight convex–concave ππ interactions. The controlled reduction of C60H28 resulted in the isolation and structural characterization of its dianion in the form of the rubidium salt that shows an entrapment of counterions by an anionic pincer.

Graphical abstract: An unsolvated buckycatcher and its first dianion

Supplementary files

Article information

Article type
Communication
Submitted
12 Dec 2013
Accepted
13 Jan 2014
First published
28 Jan 2014

Chem. Commun., 2014,50, 2657-2659

Author version available

An unsolvated buckycatcher and its first dianion

A. V. Zabula, Y. V. Sevryugina, S. N. Spisak, L. Kobryn, R. Sygula, A. Sygula and M. A. Petrukhina, Chem. Commun., 2014, 50, 2657 DOI: 10.1039/C3CC49451A

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