“Converting” an hexametallic MnIII wheel to a dodecametallic MnIII wheel via ligand oximation

Sergio Sanz; Jamie M. Frost; Mateusz B. Pitak; Simon J. Coles; Stergios Piligkos; Paul J. Lusby; Euan K. Brechin

doi:10.1039/C3CC49583C

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“Converting” an hexametallic Mn^III wheel to a dodecametallic Mn^III wheel via ligand oximation†

Sergio Sanz,^a Jamie M. Frost,^a Mateusz B. Pitak,^b Simon J. Coles,^b Stergios Piligkos,^c Paul J. Lusby^a and Euan K. Brechin*^a

Author affiliations

* Corresponding authors

^a EaStCHEM School of Chemistry, The University of Edinburgh, West Mains Road, Edinburgh, UK
E-mail: ebrechin@staffmail.ed.ac.uk

^b UK National Crystallography Service, Chemistry, Faculty of Natural and Environmental Sciences, University of Southampton, Highfield Campus, Southampton, UK

^c Department of Chemistry, University of Copenhagen, Universitetsparken 5, Denmark

Abstract

Ligand oximation “converts” an hexametallic Mn^III wheel into a dodecametallic Mn^III wheel, while the magnetic exchange switches from ferro- to antiferromagnetic.

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Article information

DOI: https://doi.org/10.1039/C3CC49583C
Article type: Communication
Submitted: 18 Dec 2013
Accepted: 07 Feb 2014
First published: 07 Feb 2014

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Chem. Commun., 2014,50, 3310-3312

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“Converting” an hexametallic Mn^III wheel to a dodecametallic Mn^III wheel via ligand oximation

S. Sanz, J. M. Frost, M. B. Pitak, S. J. Coles, S. Piligkos, P. J. Lusby and E. K. Brechin, Chem. Commun., 2014, 50, 3310 DOI: 10.1039/C3CC49583C

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