Issue 19, 2013

Mixed Cu(ii)–Bi(iii) metal organic framework with a 2D inorganic subnetwork and its catalytic activity

Abstract

The very dense (d = 4.359 g cm−3) three dimensional (3D) hybrid heterometallic framework Bi3O2Cu(OH)(pdc)2 (pdc3−:3,5-pyrazoledicarboxylate), 1, features a 2D inorganic subnetwork representing an unprecedented topological type, and is an effective catalyst for the diastereoselective synthesis of E-α,β-unsaturated ketones.

Graphical abstract: Mixed Cu(ii)–Bi(iii) metal organic framework with a 2D inorganic subnetwork and its catalytic activity

Supplementary files

Article information

Article type
Communication
Submitted
18 Dec 2012
Accepted
26 Feb 2013
First published
26 Feb 2013

CrystEngComm, 2013,15, 3776-3779

Mixed Cu(II)–Bi(III) metal organic framework with a 2D inorganic subnetwork and its catalytic activity

F. SHI, A. R. Silva, T. Yang and J. Rocha, CrystEngComm, 2013, 15, 3776 DOI: 10.1039/C3CE27056D

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