Issue 35, 2013
From the journal:

CrystEngComm

Synthesis of a phthalocyanine and porphyrin 2D covalent organic framework†

Venkata S. Pavan K. Neti,a   Xiaofei Wu,b   Shuguang Dengb  and  Luis Echegoyen*a  

* Corresponding authors

a Department of Chemistry, University of Texas at El Paso, El Paso, TX 79968, United States
E-mail: echegoyen@utep.edu
Fax: +1 915-747-8807
Tel: +1 915-747-7573

b Department of Chemical Engineering, New Mexico State University, Las Cruces, NM 88003, United States

Abstract

A new phthalocyanine and porphyrin based hybrid covalent organic framework, CoPc-PorDBA COF, has been synthesized and its gas storage properties have been measured. The CoPc-PorDBA COF crystallizes into 2D sheets with an eclipsed AA stacking motif, and it showed high surface area (SBET = 1315 m2 g−1), and can store up to 0.8 wt% of H2 at 77 K and 1 bar and 0.6 wt% of CH4 at 298 K and 1 bar.

Graphical abstract: Synthesis of a phthalocyanine and porphyrin 2D covalent organic framework

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Article information

DOI
https://doi.org/10.1039/C3CE40706C
Article type
Communication
Submitted
22 Apr 2013
Accepted
28 May 2013
First published
31 May 2013

CrystEngComm, 2013,15, 6892-6895

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Synthesis of a phthalocyanine and porphyrin 2D covalent organic framework

V. S. P. K. Neti, X. Wu, S. Deng and L. Echegoyen, CrystEngComm, 2013, 15, 6892 DOI: 10.1039/C3CE40706C

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