Issue 31, 2013
From the journal:

CrystEngComm

Arene–perfluoroarene interactions for crystal engineering of metal complexes: Controlled self-assembly of paddle-wheel dimers†

Takahiro Itoh,ab   Mio Kondo,*abcd   Mari Kanaikea  and  Shigeyuki Masaoka*abd  

* Corresponding authors

a Department of Life and Coordination-Complex Molecular Science, Institute for Molecular Science, Higashiyama 5-1, Myodaiji, Okazaki, Aichi 444-8787, Japan
E-mail: mio@ims.ac.jp, masaoka@ims.ac.jp
Fax: +81 564-59-5589
Tel: +81 564-59-5587

b The Graduate University for Advanced Studies, Shonan Village, Hayama, Kanagawa 240-0193, Japan

c ACT-C, Japan Science and Technology Agency (JST), Honcho 4-1-8, Kawaguchi, Saitama 332-0012, Japan

d Research Center of Integrative Molecular Systems (CIMoS), Institute for Molecular Science, Nishigo-naka 38, Myodaiji, Okazaki, Aichi 444-8585, Japan

Abstract

We show a new approach to control the self-assembly of paddle-wheel dimers by intermolecular multipoint arene–perfluoroarene interactions. Two types of complexes, I-shaped Rh2(O2CCF3)2(L)2(3-pentanone)2 (1) and cross-shaped Cu2(L)4(THF)2 (2) were synthesized to afford 1D chain and 2D square-grid sheet structures, respectively.

Graphical abstract: Arene–perfluoroarene interactions for crystal engineering of metal complexes: Controlled self-assembly of paddle-wheel dimers

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Article information

DOI
https://doi.org/10.1039/C3CE40777B
Article type
Communication
Submitted
02 May 2013
Accepted
30 May 2013
First published
27 Jun 2013

CrystEngComm, 2013,15, 6122-6126

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Arene–perfluoroarene interactions for crystal engineering of metal complexes: Controlled self-assembly of paddle-wheel dimers

T. Itoh, M. Kondo, M. Kanaike and S. Masaoka, CrystEngComm, 2013, 15, 6122 DOI: 10.1039/C3CE40777B

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