Issue 20, 2014
From the journal:

CrystEngComm

Pressure-induced isostructural phase transition of a metal–organic framework Co2(4,4′-bpy)3(NO3)4·xH2O†

Mi Zhou,ab   Kai Wang,*a   Zhiwei Men,b   Chenglin Sun,b   Zhanlong Li,b   Bingbing Liu,a   Guangtian Zoua  and  Bo Zou*a  

* Corresponding authors

a State Key Laboratory of Superhard Materials, Jilin university, Changchun, PR China
E-mail: zoubo@jlu.edu.cn
Fax: +86 431 85168883
Tel: +86 431 85168882

b College of Physics, Jilin university, Changchun, PR China

Abstract

Based on the 4,4′-bipyridine organic linker, metal–organic frameworks of Co2(4,4′-bpy)3(NO3)4·xH2O (CB-MOF) have been prepared. The pressure-dependent structure evolution of CB-MOF has been investigated up to 11 GPa. An isostructural phase transition was observed at about 6 GPa followed by negative compressibility along the b axis.

Graphical abstract: Pressure-induced isostructural phase transition of a metal–organic framework Co2(4,4′-bpy)3(NO3)4·xH2O

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Article information

DOI
https://doi.org/10.1039/C3CE42607F
Article type
Communication
Submitted
23 Dec 2013
Accepted
18 Feb 2014
First published
19 Feb 2014

CrystEngComm, 2014,16, 4084-4087

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Pressure-induced isostructural phase transition of a metal–organic framework Co2(4,4′-bpy)3(NO3)4·xH2O

M. Zhou, K. Wang, Z. Men, C. Sun, Z. Li, B. Liu, G. Zou and B. Zou, CrystEngComm, 2014, 16, 4084 DOI: 10.1039/C3CE42607F

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