Synthesis, crystal structure, mass spectrometry, electrochemistry and magnetism of a MnIII-substituted trilacunary Keggin tungstosilicate

Denys Shevchenko; Ping Huang; Volodymyr V. Bon; Magnus F. Anderlund; Vladimir N. Kokozay; Stenbjörn Styring; Anders Thapper

doi:10.1039/C3DT12500A

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Synthesis, crystal structure, mass spectrometry, electrochemistry and magnetism of a Mn^III-substituted trilacunary Keggin tungstosilicate†

Denys Shevchenko,*^a Ping Huang,^b Volodymyr V. Bon,^c Magnus F. Anderlund,^b Vladimir N. Kokozay,^d Stenbjörn Styring^b and Anders Thapper^b

Author affiliations

* Corresponding authors

^a Analytical Chemistry, Department of Chemistry – Biomedical Center, Uppsala University, PO Box 599, Uppsala, Sweden
E-mail: denys.shevchenko@kemi.uu.se

^b Molecular Biomimetics, Department of Chemistry – Ångström Laboratory, Uppsala University, P.O. Box 523, Uppsala, Sweden

^c V.I. Vernadskii Institute of General and Inorganic Chemistry, NAS, 32-34 Acad. Palladina Ave., Kyiv, Ukraine

^d Department of Inorganic Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska St. 64/13, Kyiv 01601, Ukraine

Abstract

A rare example of a “monomeric” triple transition-metal substituted Keggin anion has been synthesized and characterized by various methods including X-ray crystallography, ESI and MALDI mass spectrometry, electrochemistry, EPR, and SQUID.

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Article information

DOI: https://doi.org/10.1039/C3DT12500A
Article type: Paper
Submitted: 17 Sep 2012
Accepted: 24 Jan 2013
First published: 25 Jan 2013

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Dalton Trans., 2013,42, 5130-5139

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Synthesis, crystal structure, mass spectrometry, electrochemistry and magnetism of a Mn^III-substituted trilacunary Keggin tungstosilicate

D. Shevchenko, P. Huang, V. V. Bon, M. F. Anderlund, V. N. Kokozay, S. Styring and A. Thapper, Dalton Trans., 2013, 42, 5130 DOI: 10.1039/C3DT12500A

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