Indium(III)–dicarboxylic microporous frameworks with high adsorption selectivity for CO2 over N2

Wenbin Ji; Hailiang Hu; Weisong Zhang; Hui Huang; Xiaodie He; Xiao Han; Fangfang Zhao; Yang Liu; Zhenhui Kang

doi:10.1039/C3DT50822F

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Indium(iii)–dicarboxylic microporous frameworks with high adsorption selectivity for CO₂ over N₂†

Wenbin Ji,^a Hailiang Hu,^a Weisong Zhang,^a Hui Huang,^a Xiaodie He,^a Xiao Han,^a Fangfang Zhao,^a Yang Liu^a and Zhenhui Kang*^a

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* Corresponding authors

^a Institute of Functional Nano and Soft Materials (FUNSOM) and Jiangsu Key Laboratory for Carbon Based Functional Materials and Devices, Soochow University, Suzhou, Jiangsu 215123, People's Republic of China
E-mail: zhkang@suda.edu.cn
Fax: +86 512-65882846
Tel: +86 512-65880957

Abstract

Two microporous metal–organic frameworks formulated as H₂In₃O(OH)₃(1,3-bdc)₃ (1) and HIn(1,4-bdc)₂ (2) (bdc = benzenedicarboxylic) were designed and synthesized. Compound 2 shows a high adsorption selectivity for CO₂ over N₂ as well as a high stability.

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Article information

DOI: https://doi.org/10.1039/C3DT50822F
Article type: Communication
Submitted: 27 Mar 2013
Accepted: 04 Jun 2013
First published: 05 Jun 2013

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Dalton Trans., 2013,42, 10690-10693

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Indium(III)–dicarboxylic microporous frameworks with high adsorption selectivity for CO₂ over N₂

W. Ji, H. Hu, W. Zhang, H. Huang, X. He, X. Han, F. Zhao, Y. Liu and Z. Kang, Dalton Trans., 2013, 42, 10690 DOI: 10.1039/C3DT50822F

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Dalton Transactions