An unprecedented acylamide-functionalized 2D → 3D microporous metal–organic polycatenation framework exhibiting highly selective CO2 capture

Bo Liu; Dong-Sheng Li; Lei Hou; Guo-Ping Yang; Yao-Yu Wang; Qi-Zhen Shi

doi:10.1039/C3DT50997D

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An unprecedented acylamide-functionalized 2D → 3D microporous metal–organic polycatenation framework exhibiting highly selective CO₂ capture†

Bo Liu,^a Dong-Sheng Li,^ab Lei Hou,^a Guo-Ping Yang,^a Yao-Yu Wang*^a and Qi-Zhen Shi^a

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* Corresponding authors

^a Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710069, China
E-mail: wyaoyu@nwu.edu.cn
Tel: +86 29 88302604

^b College of Mechanical and Material Engineering, Research Institute of Materials, China Three Gorges University, Yichang, P. R. China

Abstract

An acylamide-functionalized 3D microporous metal–organic framework built on Zn₂ clusters with mixed H₃bcta and dipy ligands, which shows unprecedented 2D → 3D polycatenation based on dipy-pillared honeycomb bilayers, and exhibits highly selective CO₂ capture.

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Article information

DOI: https://doi.org/10.1039/C3DT50997D
Article type: Communication
Submitted: 16 Apr 2013
Accepted: 09 May 2013
First published: 10 May 2013

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Dalton Trans., 2013,42, 9822-9825

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An unprecedented acylamide-functionalized 2D → 3D microporous metal–organic polycatenation framework exhibiting highly selective CO₂ capture

B. Liu, D. Li, L. Hou, G. Yang, Y. Wang and Q. Shi, Dalton Trans., 2013, 42, 9822 DOI: 10.1039/C3DT50997D

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Dalton Transactions