Issue 34, 2013
From the journal:

Dalton Transactions

Bis(tetrabenzotriazaporphyrinato) and (tetrabenzotriazaporphyrinato)(phthalocyaninato) lutetium(iii) complexes – novel sandwich-type tetrapyrrolic ligand based NIR absorbing electrochromes†

Victor E. Pushkarev,*ab   Valery V. Kalashnikov,a   Stanislav A. Trashin,a   Nataliya E. Borisova,a   Larisa G. Tomilovaab  and  Nikolay S. Zefirovab  

* Corresponding authors

a Institute of Physiologically Active Compounds, Russian Academy of Sciences, 1 Severny proezd, 142432 Chernogolovka, Moscow Region, Russian Federation
E-mail: pushkarev@org.chem.msu.ru
Fax: +7 496 524 9508

b Department of Chemistry, M.V. Lomonosov Moscow State University, 1 Leninskie Gory, 119991 Moscow, Russian Federation
E-mail: tom@org.chem.msu.ru
Fax: +7 495 939 0290

Abstract

The first sandwich-type complexes have been prepared for tetrabenzotriazaporphyrin ligands. The compounds reveal intrinsic UV-Vis/NIR absorption as well as peculiar electrochromic behavior. The heteroleptic (tetrabenzotriazaporphyrinato)(phthalocyaninato) lutetium derivative shows intermediate spectral and electrochemical properties with respect to homoleptic relatives.

Graphical abstract: Bis(tetrabenzotriazaporphyrinato) and (tetrabenzotriazaporphyrinato)(phthalocyaninato) lutetium(iii) complexes – novel sandwich-type tetrapyrrolic ligand based NIR absorbing electrochromes

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Article information

DOI
https://doi.org/10.1039/C3DT51357B
Article type
Communication
Submitted
24 May 2013
Accepted
17 Jun 2013
First published
17 Jun 2013

Dalton Trans., 2013,42, 12083-12086

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Bis(tetrabenzotriazaporphyrinato) and (tetrabenzotriazaporphyrinato)(phthalocyaninato) lutetium(III) complexes – novel sandwich-type tetrapyrrolic ligand based NIR absorbing electrochromes

V. E. Pushkarev, V. V. Kalashnikov, S. A. Trashin, N. E. Borisova, L. G. Tomilova and N. S. Zefirov, Dalton Trans., 2013, 42, 12083 DOI: 10.1039/C3DT51357B

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