Issue 31, 2013
From the journal:

Dalton Transactions

A theoretical study on the ring expansion of NHCs by silanes†

Kalon J. Iversen,a   David J. D. Wilson*a  and  Jason L. Dutton*a  

* Corresponding authors

a Department of Chemistry, La Trobe Institute for Molecular Science, La Trobe University, Melbourne, Victoria, Australia
E-mail: david.wilson@latrobe.edu.au, j.dutton@latrobe.edu.au

Abstract

A theoretical study focusing on the ring expansion that occurs in the reaction of N-heterocyclic carbenes with silanes has been carried out. A detailed reaction pathway was determined which indicates that formation of C–H bonds is the crucial factor in the transformation.

Graphical abstract: A theoretical study on the ring expansion of NHCs by silanes

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Article information

DOI
https://doi.org/10.1039/C3DT51503F
Article type
Communication
Submitted
06 Jun 2013
Accepted
18 Jun 2013
First published
19 Jun 2013

Dalton Trans., 2013,42, 11035-11038

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A theoretical study on the ring expansion of NHCs by silanes

K. J. Iversen, D. J. D. Wilson and J. L. Dutton, Dalton Trans., 2013, 42, 11035 DOI: 10.1039/C3DT51503F

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