Issue 38, 2013
From the journal:

Dalton Transactions

Sumanenylferrocenes and their solid state self-assembly†

Berit Topolinski,ab   Bernd M. Schmidt,ab   Shuhei Higashibayashi,b   Hidehiro Sakuraib  and  Dieter Lentz*a  

* Corresponding authors

a Freie Universität Berlin, Fabeckstrasse 34-36, D-14195, Berlin, Germany
E-mail: dlentz@zedat.fu-berlin.de
Fax: +49-30-838-52590
Tel: +49-30-838-52695

b Institute for Molecular Science, Myodaiji, 444-8787 Okazaki, Japan
Fax: +81 564595527
Tel: +81 564595525

Abstract

The first ferrocene-fused organometallic compounds derived from the buckybowl sumanene (C21H12) are presented. Both compounds, sumanenylferrocene and 1,1′-disumanenylferrocene, have been synthesized by Negishi-type cross-coupling of iodosumanene and were studied crystallographically. Sumanenylferrocenes form unique packing motifs, which are both different from those of their corannulene congeners and sumanene itself.

Graphical abstract: Sumanenylferrocenes and their solid state self-assembly

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Article information

DOI
https://doi.org/10.1039/C3DT51569A
Article type
Communication
Submitted
13 Jun 2013
Accepted
09 Aug 2013
First published
12 Aug 2013

Dalton Trans., 2013,42, 13809-13812

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Sumanenylferrocenes and their solid state self-assembly

B. Topolinski, B. M. Schmidt, S. Higashibayashi, H. Sakurai and D. Lentz, Dalton Trans., 2013, 42, 13809 DOI: 10.1039/C3DT51569A

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