Issue 37, 2013
From the journal:

Dalton Transactions

A decatungstate-type polyoxoniobate with centered manganese: [H2MnIVNb10O32]8− as a soluble tetramethylammonium salt†

Jung-Ho Son*a  and  William H. Casey*ab  

* Corresponding authors

a Department of Chemistry, University of California, Davis, One Shields Ave., Davis, CA 95616, USA
E-mail: junghoson@gmail.com, whcasey@ucdavis.edu
Fax: (+1) (530) 752 8995
Tel: (+1) (530) 752 3211

b Department of Geology, University of California, Davis, One Shields Ave., Davis, CA 95616, USA

Abstract

A highly symmetric MnIV-centered polyoxoniobate [H2MnIVNb10O32]8− was synthesized via hydrothermal methods as a soluble tetramethylammonium salt. The structure is similar to decatungstate structure [W10O32]4−, except for the central heteroatom. The cluster is stable between 4 < pH < 10, as was characterized with ESI-MS and UV-Vis spectroscopy.

Graphical abstract: A decatungstate-type polyoxoniobate with centered manganese: [H2MnIVNb10O32]8− as a soluble tetramethylammonium salt

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Article information

DOI
https://doi.org/10.1039/C3DT51798E
Article type
Communication
Submitted
03 Jul 2013
Accepted
31 Jul 2013
First published
01 Aug 2013
This article is Open Access
Creative Commons BY license

Dalton Trans., 2013,42, 13339-13342

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A decatungstate-type polyoxoniobate with centered manganese: [H2MnIVNb10O32]8− as a soluble tetramethylammonium salt

J. Son and W. H. Casey, Dalton Trans., 2013, 42, 13339 DOI: 10.1039/C3DT51798E

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