Issue 38, 2013
From the journal:

Dalton Transactions

Organosilicon linkers in metal organic frameworks: the tetrahedral tetrakis(4-tetrazolylphenyl)silane ligand†

Ivan Timokhin,ab   Júlia Baguña Torres,a   Andrew J. P. White,a   Paul D. Lickiss,a   Claudio Pettinarib  and  Robert P. Davies*a  

* Corresponding authors

a Department of Chemistry, Imperial College London, South Kensington, London, UK
E-mail: r.davies@imperial.ac.uk

b Scuola del Farmaco e dei Prodotti della Salute, Università degli Studi di Camerino, via S. Agostino 1, I-62032 Camerino, MC, Italy

Abstract

Formal substitution of the central carbon by silicon within the tetrahedral tetrakis(4-tetrazolylphenyl)methane linker in a copper-based MOF is shown to uniquely influence the structure of the resultant MOF, affecting the orientation of the metal-based nodes and leading to an increase in unit-cell volume and solvent accessible void space.

Graphical abstract: Organosilicon linkers in metal organic frameworks: the tetrahedral tetrakis(4-tetrazolylphenyl)silane ligand

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Article information

DOI
https://doi.org/10.1039/C3DT51863A
Article type
Communication
Submitted
16 Jul 2013
Accepted
09 Aug 2013
First published
20 Aug 2013

Dalton Trans., 2013,42, 13806-13808

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Organosilicon linkers in metal organic frameworks: the tetrahedral tetrakis(4-tetrazolylphenyl)silane ligand

I. Timokhin, J. Baguña Torres, A. J. P. White, P. D. Lickiss, C. Pettinari and R. P. Davies, Dalton Trans., 2013, 42, 13806 DOI: 10.1039/C3DT51863A

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